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M Suresh, SA Bahadur, S Athimoolam – Materials Science-Poland, 2019

Abstract

In the present work, a new organic second order NLO material: L-isoleucinium p-toluenesulfonate monohydrate (LIPT) is synthesized and reported for the first time. The LIPT is crystallized in a non-centrosymmetric monoclinic space group P21. Structural and hydrogen bond nature of the compound is analyzed using single crystal X-ray diffraction studies. The crystal exhibits very good optical properties such as wide optical transparency in the region of 210 nm to 1100 nm and the ultraviolet wavelengthemission( =283nm). Thesecond harmonic generation efficiency is found to be 1. Good thermal, mechanical properties and low dielectric constant at high frequency range show that the material may be a potential candidate for optoelectronic applications.

… Fig. 9. Photoluminescence spectrum of LIPT. collected at an angle 90° and passed through 532nm interference filter to remove IR com- ponents and fed to optical fiber based UV-Vis spectrophotometer (Black Comet C-SR, Stellarnet, USA) to measure the intensity …

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